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Technical Paper

Simulation of Catalytic Oxidation and Selective Catalytic NOx Reduction in Lean-Exhaust Hybrid Vehicles

2012-04-16
2012-01-1304
We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel-powered hybrid and plug-in hybrid vehicles (HEVs and PHEVs). The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of commercially available Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust.
Journal Article

Simulated Fuel Economy and Emissions Performance during City and Interstate Driving for a Heavy-Duty Hybrid Truck

2013-04-08
2013-01-1033
We compare the simulated fuel economy and emissions for both conventional and hybrid class 8 heavy-duty diesel trucks operating over multiple urban and highway driving cycles. Both light and heavy freight loads were considered, and all simulations included full aftertreatment for NOx and particulate emissions controls. The aftertreatment components included a diesel oxidation catalyst (DOC), urea-selective catalytic NOx reduction (SCR), and a catalyzed diesel particulate filter (DPF). Our simulated hybrid powertrain was configured with a pre-transmission parallel drive, with a single electric motor between the clutch and gearbox. A conventional heavy duty (HD) truck with equivalent diesel engine and aftertreatment was also simulated for comparison. Our results indicate that hybridization can significantly increase HD fuel economy and improve emissions control in city driving. However, there is less potential benefit for HD hybrid vehicles during highway driving.
Technical Paper

Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst in Lean Gasoline Engine Exhaust

2015-04-14
2015-01-1008
Ethanol is a very effective reductant for nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environments. With the widespread availability of ethanol/gasoline-blended fuel in the U.S., lean gasoline engines equipped with Ag/Al2O3 catalysts have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for evaluation of catalyst performance.
Technical Paper

Selective Catalytic Reduction of NOx Emissions from a 5.9 Liter Diesel Engine Using Ethanol as a Reductant

2003-10-27
2003-01-3244
NOx emissions from a heavy-duty diesel engine were reduced by more than 90% and 80% utilizing a full-scale ethanol-SCR system for space velocities of 21000/h and 57000/h respectively. These results were achieved for catalyst temperatures between 360 and 400°C and for C1:NOx ratios of 4-6. The SCR process appears to rapidly convert ethanol to acetaldehyde, which subsequently slipped past the catalyst at appreciable levels at a space velocity of 57000/h. Ammonia and N2O were produced during conversion; the concentrations of each were higher for the low space velocity condition. However, the concentration of N2O did not exceed 10 ppm. In contrast to other catalyst technologies, NOx reduction appeared to be enhanced by initial catalyst aging, with the presumed mechanism being sulfate accumulation within the catalyst. A concept for utilizing ethanol (distilled from an E-diesel fuel) as the SCR reductant was demonstrated.
Journal Article

Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines

2017-03-28
2017-01-0868
We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.
Journal Article

Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Mixing Controlled Compression Ignition Combustion

2019-04-02
2019-01-0570
Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.
Technical Paper

SULEV and “Off-Cycle” Emissions Benefits of a Vacuum-Insulated Catalytic Converter

1999-03-01
1999-01-0461
In previous SAE papers, the initial development and testing of a vacuum-insulated catalytic converter was presented. This paper provides an update of the converter development and an analysis of potential off-cycle emissions savings. Hot vibration, cool-down, and 1975 Federal Test Procedure (FTP-75) emissions test results are provided to demonstrate the effectiveness of design improvements in greatly increasing durability while retaining performance. Using standard drive cycles and “real-world” driving statistics with a vehicle simulator (ADVISOR©), catalyst temperature and vehicle exhaust emissions of a sport utility vehicle (SUV) were predicted for 16 days of driving (107 trips, 770 total miles). Compared to the baseline vehicle with a conventional catalytic converter, the SUV with a vacuum-insulated converter produced 66% less non-methane hydrocarbon (NMHC), 65% less carbon monoxide (CO), and 60% less oxides of nitrogen (NOx).
Technical Paper

SI Engine Trends: A Historical Analysis with Future Projections

2015-04-14
2015-01-0972
It is well known that spark ignited engine performance and efficiency is closely coupled to fuel octane number. The present work combines historical and recent trends in spark ignition engines to build a database of engine design, performance, and fuel octane requirements over the past 80 years. The database consists of engine compression ratio, required fuel octane number, peak mean effective pressure, specific output, and combined unadjusted fuel economy for passenger vehicles and light trucks. Recent trends in engine performance, efficiency, and fuel octane number requirement were used to develop correlations of fuel octane number utilization, performance, specific output. The results show that historically, engine compression ratio and specific output have been strongly coupled to fuel octane number.
Journal Article

RouteE: A Vehicle Energy Consumption Prediction Engine

2020-04-14
2020-01-0939
The emergence of connected and automated vehicles and smart cities technologies create the opportunity for new mobility modes and routing decision tools, among many others. To achieve maximum mobility and minimum energy consumption, it is critical to understand the energy cost of decisions and optimize accordingly. The Route Energy prediction model (RouteE) enables accurate estimation of energy consumption for a variety of vehicle types over trips or sub-trips where detailed drive cycle data are unavailable. Applications include vehicle route selection, energy accounting and optimization in transportation simulation, and corridor energy analyses, among others. The software is a Python package that includes a variety of pre-trained models from the National Renewable Energy Laboratory (NREL). However, RouteE also enables users to train custom models using their own data sets, making it a robust and valuable tool for both fast calculations and rigorous, data-rich research efforts.
Journal Article

Review: Fuel Volatility Standards and Spark-Ignition Vehicle Driveability

2016-03-14
2016-01-9072
Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.
Technical Paper

Review of Diesel Exhaust Aftertreatment Programs

1999-04-27
1999-01-2245
The DOE Office of Heavy Vehicle Technologies (OHVT) and its predecessor organizations have maintained aggressive projects in diesel exhaust aftertreatment since 1993. The Energy Policy Act of 1992, Section 2027, specifically authorized DOE to help accelerate the ability of U. S. diesel engine manufacturers to meet emissions regulations while maintaining the compression ignition engines inherently high efficiency. A variety of concepts and devices have been evaluated for NOx and Particulate matter (PM) control. Additionally, supporting technology in diagnostics for catalysis, PM measurement, and catalyst/reductant systems are being developed. This paper provides a summary of technologies that have been investigated and provides recent results from ongoing DOE-sponsored R&D. NOx control has been explored via active NOx catalysis, several plasma-assisted systems, electrochemical cells, and fuel additives.
Technical Paper

Resolving EGR Distribution and Mixing

2002-10-21
2002-01-2882
A minimally invasive spatially resolved capillary inlet mass spectrometer has been used to quantify EGR/air mixing in a Cummins V-8 medium-duty diesel engine. Two EGR-system hardware designs were evaluated in terms of EGR-air mixing at the intake manifold inlet and port-to-port EGR charge uniformity. Performance was assessed at four modalized-FTP engine conditions. One design is found to be considerably better, particularly at three of the four engine conditions. Specific questions such as the effect of maximizing mass air flow on EGR mixing, and if particular cylinders are EGR starved are investigated. The detailed performance characteristics suggest areas to focus improvement efforts, and serve as a foundation for identifying the non-uniformity EGR barriers and origins.
Journal Article

Residual Stress Mapping along the Cylinder Bores of Al Alloy Engine Blocks Subjected to Production Solution Heat Treatment Schedule

2014-04-01
2014-01-0837
The development of an optimized heat treatment schedule, with the aim of maximizing strength and relieving tensile residual stress, is important to prevent in-service cylinder distortion in Al alloy engine blocks containing cast-in gray iron liners. However, to effectively optimize the engine block heat treatment schedule, the current solutionizing parameters must be analyzed and compared to the as-cast condition to establish a baseline for residual stress relief. In this study, neutron diffraction was carried out to measure the residual stress along the aluminum cylinder bridge following solution heat treatment. The stresses were measured in the hoop, radial and axial orientations and compared to a previous measured as-cast (TSR) engine block. The results suggest that solution heat treatment using the current production parameters partially relieved tensile residual stress in the Al cylinder bridge, with stress relief being more effective near the bottom of the cylinder.
Technical Paper

Residual Stress Distribution in a Hydroformed Advanced High Strength Steel Component: Neutron Diffraction Measurements and Finite Element Simulations

2018-04-03
2018-01-0803
Today’s automotive industry is witnessing increasing applications of advanced high strength steels (AHSS) combined with innovative manufacturing techniques to satisfy fuel economy requirements of stringent environmental regulations. The integration of AHSS in novel automotive structure design has introduced huge advantages in mass reduction while maintaining their structural performances, yet several concerns have been raised for this relatively new family of steels. One of those concerns is their potentially high springback after forming, which can lead to geometrical deviation of the final product from its designed geometry and cause difficulties during assembly. From the perspective of accurate prediction, control and compensation of springback, further understanding on the effect of residual stress in AHSS parts is urged. In this work, the residual stress distribution in a 980GEN3 steel part after hydroforming is investigated via experimental and numerical approaches.
Technical Paper

Residual Stress Analysis for Additive Manufactured Large Automobile Parts by Using Neutron and Simulation

2020-04-14
2020-01-1071
Metal additive manufacturing has high potential to produce automobile parts, due to its shape flexibility and unique material properties. On the other hand, residual stress which is generated by rapid solidification causes deformation, cracks and failure under building process. To avoid these problems, understanding of internal residual stress distribution is necessary. However, from the view point of measureable area, conventional residual stress measurement methods such as strain gages and X-ray diffractometers, is limited to only the surface layer of the parts. Therefore, neutron which has a high penetration capability was chosen as a probe to measure internal residual stress in this research. By using time of flight neutron diffraction facility VULCAN at Oak Ridge National Laboratory, residual stress for mono-cylinder head, which were made of aluminum alloy, was measured non-distractively. From the result of precise measurement, interior stress distribution was visualized.
Technical Paper

Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

2005-05-11
2005-01-2193
Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).
Journal Article

Reduction of Hot Tears: Alloy and Casting Process Optimization Using Neutron Diffraction

2010-04-12
2010-01-0748
The continued need of vehicle weight reduction provides impetus for research into the development of novel automotive casting alloys and their processing technologies. Where possible, ferrous components are being replaced by aluminum (Al) and magnesium (Mg) alloy counterparts. This transition, however, requires a systematic optimization of the alloys and their manufacturing processes to enable production of defect-free castings. In this context, prevention of hot tears remains a challenge for Al and Mg alloy thin-wall castings. Hot tears form in semi-solid alloy subjected to localized tensile stress. Classical methods of stress measurement present numerous experimental limitations. In this research, neutron diffraction (ND) was used as a novel tool to obtain stress maps of castings and to quantify the effect of two processes used to eliminate hot tears in permanent mold castings: 1) increasing of the mold temperature during casting of Mg alloys, and 2) grain refinement of Al alloys.
Technical Paper

Reduction in Vehicle Temperatures and Fuel Use from Cabin Ventilation, Solar-Reflective Paint, and a New Solar-Reflective Glazing

2007-04-16
2007-01-1194
A new type of solar-reflective glass that improves reflection of the near-infrared (NIR) portion of the solar spectrum has been developed. Also developed was a prototype solar-reflective paint that increases the NIR reflection of opaque vehicle surfaces while maintaining desired colors in the visible portion of the spectrum. Both of these technologies, as well as solar-powered parked car ventilation, were tested on a Cadillac STS as part of the Improved Mobile Air Conditioning Cooperative Research Program (I-MAC). Significant reductions in interior and vehicle skin temperatures were measured. The National Renewable Energy Laboratory (NREL) performed an analysis to determine the impact of reducing the thermal load on the vehicle. A simplified cabin thermal/fluid model was run to predict the potential reduction in A/C system capacity. The potential reduction in fuel use was calculated using a vehicle simulation tool developed by the U.S. Department of Energy (DOE).
Technical Paper

Recycling of New Generation Vehicles

1999-03-01
1999-01-0673
The composition of New Generation Vehicles under the Partnership for a New Generation of Vehicles (PNGV) program is anticipated to be significantly different from the typical automobile available now on the market. A spreadsheet cost model of the automobile recycling infrastructure was developed to estimate the potential effects of New Generation Vehicles on the future economic viability of the recycling industry. On the one hand, the higher value of aluminum is likely to cause a positive impact on the three distinct players in the recycling industry, if some technical issues are overcome. On the other hand, the economic viability of the current recycling industry may be diminished by the substitution of composites.
Technical Paper

Reasons for changes in MPG Estimates, Model Year 1978 to the Present

1984-02-01
840500
In model year 1983, new car MPG declined for the first time in ten years. Accompanying this decline in MPG, the size of the average car increased, car weights and engine sizes increased and diesel sales declined - all reversing their movements over the previous ten years. Using carline MPG estimates and sales figures, it is estimated that new car MPG declined 0.29 in 1983 after rising 6.70 MPG over the previous four years. Furthermore, it is estimated that actions by new car buyers would have lowered the 1983 MPG 0.40 MPG through the purchase of larger cars, cars with larger engines and fewer diesel engines if the manufacturers had not made some fuel economy improvements and introduced some new high-MPG cars. A simple model of future fuel use increases as a function of MPG levels below a specified level consistent with the CAFE standards shows that the costs of lower fuel economy will only gradually be felt, but that these costs will increase over time and persist for over a decade.
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